Kinetics Analysis of X65 Steel corrosion reactions at the simultaneous presence of CO2 and H2S

Document Type : Research Paper

Authors

Department of Materials Engineering, Isfahan University of Technology

10.22034/ijissi.2021.243776

Abstract

In this research, the effect of fluid velocity on corrosion kinetics of X65 steel has been investigated in an aqueous solution containing CO2 and H2S according to the steel structures corrosion sensitivity in aqueous environments. Therefore, the aqueous solution saturated with CO2 and containing 50 ppm of H2S was used to perform the corrosion tests. The fluid velocity varied between 0 to 1000 rpm, and the tests were carried out at three different temperatures of 25, 45, and 65oC. During these tests at various periods, parameters like the iron ion concentration (iron count) (ICP) and instant corrosion rate using the LPR test were monitored. The corrosion products were characterized using XRD and SEM methods. Also, the kinetics and mechanism of the corrosion process were analyzed in these conditions. The results at various fluid velocities showed that the first layer containing mostly mackinawite does not have the appropriate density, in such a way that the porosities and micro-cracks can be a suitable route for corrosive ions to penetrate to the steel surface. Then, as time passed and the thickness of the corrosion product film increased, the number of porosities decreased; this led to the compactness of the product film and resulted in the decrease of diffusion and ion exchange in the interface and consequently the corrosion rate.

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References

[1] J. Sun, C. Sun, G. Zhang, X. Li, W. Zhao, T. Jiang, H. Liu, X. Cheng, Y. Wang A, Corros. Sci., 107 (2016): 31-40.
[2] A. Dugstad, B. Morland, S. Clausen, Corrosion Conference, (2011), Paper No. 11070, NACE, Houston, TX.
[3] I.S. Cole, P. Corrigan, S. Sim, N. Birbilis, INT J GREENH GAS CON, 5.4 (2011): 749-756.
[4] A. Kahyarian, M. Achour, S. Nesic, Corrosion Conference, Houston Tx, (2017): 149-190.
[5] J. Kvarekval, R. Nyborg, H. Choi, Corrosion Conference, Paper No. 03339, NACE, Houston, TX, (2003).
[6] I.H. Omar, Y.M. Gunaltun, J. Kvarekval, A. Dugstad, Corrosion Conference, Paper No.05300, NACE, Houston, TX, (2005).
[7] A.S. Ruhl, A. Kranzmann, Int. J. Greenh. Gas Control 9 (2012) 85-90.
[8] Y.S. Choi, S. Nesic, Corrosion Conference, Paper No.10196, NACE, Houston, TX, (2010).
[9] Nešić, S., Postlethwaite, J., & Olsen, S., Corros, 52.4 (1996) 280-294.
[10] D.W.Shoesmith, P. Taylor, M.G. Bailey, D. Owen, J. Electrochem. Soc., 127.5 (1980): 1007.
[11] S. Navabzade Esmaeely, G.Bota, B. Brown, S.Nesic,  Corrosion Conference, Houston Tx, 74.1 (2018): 37-49.
[12] W. Sun and S. Nesic, Corrosion Conference, Paper No. 07655, 19 (2007).
[13] Champion Technologies: “Corrosion Mitigation for Complex Environments”. Houston: Champion Technologies; (2012).
[14] AJ. Brito, AT.Dealmeida,, Reliab. Eng. Syst. 94.2 (2009) 187-198.
[15] S. Nesic, H. Li, J. Huang, D. Sormaz, Corrosion Conference, Paper No. 09572, (2009).
[16] W. Sun, S. Nesic, Corrosion, 65.5 (2009) 291-307.
[17] Y.S. Choi, S. Nesic, S. Ling, Electrochim. Acta, 56.4 (2011) 1752-1760.
[18] P.C. Okonkwo, M.H. Sliem, R.A. Shakoor, J. Mater. Eng 26.8 (2017) 3775-3783.
[19] N. Yaakob, F. Farelas, M. Singer, S. Nesic, D. Young, Corrosion Conference, Paper No. 7695, (2016).
[20] B. Brown, “H2S/CO2 Corrosion in Multiphase Flow”, Ohio University Advisory Board Meeting Report, Internal Report to be Published, 2006.
[21] M. Schutze, “Protective Oxide Scales and Their Breakdown”, John Wiley & Sons, Chichester, (1997).
[22] S. Navabzade Esmaeely, W. Zhang, B. Brown, Corrosion Conference, Houston Tx, 73.9 (2017) 1098-1106.
[23] M. Schoenitz, B. Patel, O. Agboh and E. L. Dreizin, Thermochimica Acta 507 (2010): 115-122.
[24] R. F. Speyer, “Thermal Analysis of Materials”, Marcel Dekker Inc., New York, (1993).
[25] M. Schoenitz, C. M. Chen, X. Zhu, and E. L. Dreizin, 40th International Conference of ICT, Karlsruhe, Germany, 34 (2009) 1–11.
[26] N. Pilling and R. Bedworth, J. Inst. Metals, 29 (1923) 529.
[27] R. Winston Revie, H. Uhlig, “Corrosion and Corrosion Control”, 4th Edition.
[28] M. Golahan, D. Young, M. Singer, and R.P. Nogueira, “Black Powder Formation by Dewing and Hygroscopic Corrosion Processes”, J Nat Gas Sci Eng, 56 (2018): 358-367.

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